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. 2010 Jul 7;66(Pt 8):m889.
doi: 10.1107/S1600536810025705.

Diaqua-(1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N,N,N)copper(II) bis-(2,3,4,5,6-penta-fluoro-benzoate) dihydrate

Nur Syamimi Ahmad Tajidi  1 , Norbani Abdullah, Zainudin Arifin, Kong Wai Tan, Seik Weng Ng
Affiliations

Diaqua-(1,4,8,11-tetra-aza-cyclo-tetra-decane-κN,N,N,N)copper(II) bis-(2,3,4,5,6-penta-fluoro-benzoate) dihydrate

Nur Syamimi Ahmad Tajidi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Cu(II) atom in the title salt, [Cu(C(10)H(24)N(4))(H(2)O)(2)](C(6)F(5)CO(2))(2)·2H(2)O, is chelated by the four N atoms of the 1,4,8,11-tetra-aza-cyclo-tetra-decane (cyclam) ligand and is coordinated by two water mol-ecules in a Jahn-Teller-type tetra-gonally distorted octa-hedral geometry. The Cu(II) atom lies on a center of inversion. The cations, anions and uncoordinated water mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds, forming a layer structure parallel to (001).

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Figures

Fig. 1.
Fig. 1.
Anisotropic displacement ellipsoid plot (Barbour, 2001) of [Cu(H2O)2(C10H24N4)]2+ 2(C6F5CO2)-.2H2O at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
See this image and copyright information in PMC

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