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. 2010 Jul 10;66(Pt 8):m915-6.
doi: 10.1107/S160053681002667X.

[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-olato-κO,O](η-norbornadiene)rhodium(I)

Mohamed Anoir Harrad, Brahim Boualy, Mustapha Ait Ali, Larbi El Firdoussi, Corrado Rizzoli

[(1R,4S)-(+)-3-Benzoyl-1,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-olato-κO,O](η-norbornadiene)rhodium(I)

Mohamed Anoir Harrad et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex mol-ecule, [Rh(C(17)H(19)O(2))(C(7)H(8))], the rhodium(I) metal centre is coordinated by the O atoms of a benzoyl-camphorate anion and the C=C bonds of the norbornadiene mol-ecule into a slightly distorted square-planar coordination geometry. The six-membered chelate ring is essentially planar (r.m.s. deviation = 0.0378 Å) and forms a dihedral angle of 31.67 (11)° with the phenyl ring.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound. Displacement ellipsoids are drawn at the 40% probability level.
Fig. 2.
Fig. 2.
Crystal packing of the title compound viewed approximately along the a axis.
See this image and copyright information in PMC

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