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. 2010 Jul 7;66(Pt 8):o1945.
doi: 10.1107/S1600536810024554.

2-Amino-anilinium 2-chloro-acetate

A Srinivasa Rao  1 , Bharat Kumar Tripuramallu, Kishore Ravada, Samar K Das
Affiliations

2-Amino-anilinium 2-chloro-acetate

A Srinivasa Rao et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the crystal structure of the title compound, C(6)H(9)N(2) (+)·ClCH(2)COO(-), prepared by the reaction of OPDA (orthophenelynediamine) with chloro-acetic -acid, N-H⋯O hydrogen bonds generate ladder-like chains and very weak inter-molecular C-H⋯Cl hydrogen-bonding inter-actions between the anions and cations lead to a supra-molecular network. C-H⋯O inter-actions also occur.

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Figures

Fig. 1.
Fig. 1.
ORTEP diagram of the compound 1 (Thermal ellipsoids are at 50% probability level).
Fig. 2.
Fig. 2.
Interactions of C—H···cl in the compound 1 give rise to diverse supramolecular network and all the inetractions arround the cation and anion respectively with symetry codes All the symetry codes for hyderogen bonding were written in the Table 1
Fig. 3.
Fig. 3.
The ladder-type one-dimensional chainlike arrangement generated by N—H···O hydrogen bonding interactions.
Fig. 4.
Fig. 4.
Hydrogen bonding situation around the cation.
Fig. 5.
Fig. 5.
Hydrogen bonding situation around the anion.
Fig. 6.
Fig. 6.
The formation of the title compound.
See this image and copyright information in PMC

References

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