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. 2010 Jul 31;66(Pt 8):o2186.
doi: 10.1107/S1600536810030138.

N-(4-Chloro-phen-yl)-4-methyl-pyridin-2-amine

Zainal A Fairuz  1 , Zaharah Aiyub, Zanariah Abdullah, Seik Weng Ng, Edward R T Tiekink
Affiliations

N-(4-Chloro-phen-yl)-4-methyl-pyridin-2-amine

Zainal A Fairuz et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(12)H(11)ClN(2), the dihedral angle between the benzene and pyridyl rings is 48.03 (8)°. Twists are also evident in the mol-ecule, in particular about the N(a)-C(b) (a = amine and b = benzene) bond [C-N-C-C = -144.79 (18)°]. In the crystal, inversion dimers linked by pairs of N-H⋯N hydrogen bonds result in the formation of eight-membered {⋯NCNH}(2) synthons [or R(2) (2)(8) loops].

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) showing displacement ellipsoids at the 35% probability level.
Fig. 2.
Fig. 2.
Unit-cell contents shown in projection down the b axis in (I). The N–H···N hydrogen bonding is shown as orange dashed lines.
See this image and copyright information in PMC

References

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