(1E,2E)-1,2-Bis(2,2-diphenyl-hydrazin-1-yl-idene)ethane
- PMID: 21588692
- PMCID: PMC3007945
- DOI: 10.1107/S1600536810032198
(1E,2E)-1,2-Bis(2,2-diphenyl-hydrazin-1-yl-idene)ethane
Abstract
In the crystal structure of the title compound, C(26)H(22)N(4), the mol-ecule is located on an inversion centre and shows an E configuration with respect to each C=N bond. The dihedral angle between the phenyl rings in the diphenyl-hydrazone group is 83.69 (11)°. These two rings make dihedral angles of 30.53 (15) and 84.53 (16)° with the central N-N=C-C=N-N dihydrazonoethane plane. Inter-molecular C-H⋯π inter-actions are observed.
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References
-
- Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–19.
-
- Angell, S. E., Rogers, C. W., Zhang, Y., Wolf, M. O. & Jones, W. E. Jr (2006). Coord. Chem. Rev.250, 1829–1841.
-
- Clulow, A. J., Selby, J. D., Cushion, M. G., Schwarz, A. D. & Mountford, P. (2008). Inorg. Chem.47, 12049–12062. - PubMed
-
- Farrugia, L. J. (1997). J. Appl. Cryst.30, 565.
-
- Farrugia, L. J. (1999). J. Appl. Cryst.32, 837–838.
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