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. 2010 Nov 24;66(Pt 12):m1639-40.
doi: 10.1107/S1600536810047367.

Chlorido{2-[(dimethyl-amino)-methyl]phenyl-κC,N}(1-methyl-1H-imidazole-κN)palladium(II)

Jason W Clements  1 , Milorad Stojanovic, Norris W Hoffman, Richard E Sykora
Affiliations

Chlorido{2-[(dimethyl-amino)-methyl]phenyl-κC,N}(1-methyl-1H-imidazole-κN)palladium(II)

Jason W Clements et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Pd(C(9)H(12)N)Cl(C(4)H(6)N(2))], which was synthesized from the reaction of 1-methyl-imidazole with dimeric dichloridobis[2-(dimethyl-amino)-benz-yl]palla-dium(II), the ring-deprotonated N,N-dimethyl-benzyl-amine ligand acts in a C,N-bidentate fashion. The dihedral angle between the ring of the 1-methyl-imidazole ligand and the palladacycle plane is 57.88 (16)°. The two N atoms from the N,N-dimethyl-benzyl-amine and 1-methyl-imidazole ligands are trans coordinated to the Pd(II) atom.

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Figures

Fig. 1.
Fig. 1.
A thermal ellipsoid plot (50%) of I showing the labeling scheme.
See this image and copyright information in PMC

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