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. 2010 Nov 20;66(Pt 12):o3246.
doi: 10.1107/S1600536810046003.

(4-Acetyl-phenolato)(subphthalo-cyaninato)boron(III)

Andrew S Paton, Alan J Lough, Timothy P Bender

(4-Acetyl-phenolato)(subphthalo-cyaninato)boron(III)

Andrew S Paton et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(32)H(19)BN(6)O(2), the B atom adopts a BON(3) tetra-hedral coordination geometry. In the crystal, pairs of mol-ecules are associated through aromatic π-π stacking inter-actions between the concave faces of the boronsubphthalocyanine fragments at a centroid-centroid distance of 3.4951 (19) Å and a weaker inter-action of the same type between the convex faces of the same group [centroid-centroid separation = 3.5669 (18) Å] also occurs.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of AcPhO-BsubPc with displacement ellipsoids drawn at the 30% probability level.
Fig. 2.
Fig. 2.
Extended crystal structure of AcPhO-BsubPc shown from two perspectives (side and end).
See this image and copyright information in PMC

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