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. 2011 Jul 21;47(27):7860-2.
doi: 10.1039/c1cc12047f. Epub 2011 Jun 3.

N-heterocyclic carbene catalyzed direct carbonylation of dimethylamine

Xiaonian Li  1 , Kun Liu, Xiaoliang Xu, Lei Ma, Hong Wang, Dahao Jiang, Qunfeng Zhang, Chunshan Lu
Affiliations

N-heterocyclic carbene catalyzed direct carbonylation of dimethylamine

Xiaonian Li et al. Chem Commun (Camb). .

Abstract

N-Heterocyclic carbene (NHC) catalyzed direct carbonylation of dimethylamine leading to the formation of DMF was successfully accomplished under metal-free conditions. The catalytic efficiency was investigated and the turnover numbers can reach as high as >300. The possible mechanism was also proposed.

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