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. 2011 Jul 15;76(14):5821-4.
doi: 10.1021/jo102423c. Epub 2011 Jun 13.

Diastereoselectivity switch in cooperatively catalyzed three-component reactions of an aryldiazoacetate, an alcohol, and a β,γ-unsaturated α-keto ester

Jingjing Ji  1 , Xia Zhang, Yingguang Zhu, Yu Qian, Jing Zhou, Liping Yang, Wenhao Hu
Affiliations

Diastereoselectivity switch in cooperatively catalyzed three-component reactions of an aryldiazoacetate, an alcohol, and a β,γ-unsaturated α-keto ester

Jingjing Ji et al. J Org Chem. .

Abstract

A highly switchable,diastereoselectivity-controlled, three-component reaction of aryldiazoacetate, alcohol,and β,γ-unsaturated α-keto esters has been achieved through a dual-metal cooperative catalysis strategy.

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