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. 2011 Apr 1;67(Pt 4):m418.
doi: 10.1107/S1600536811008142. Epub 2011 Mar 9.

(4,5-Diaza-fluoren-9-one-κN,N')bis-(thio-cyanato-κS)mercury(II)

Behrouz Notash  1 , Nasser Safari, Vahid Amani
Affiliations

(4,5-Diaza-fluoren-9-one-κN,N')bis-(thio-cyanato-κS)mercury(II)

Behrouz Notash et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Hg(NCS)(2)(C(11)H(6)N(2)O)], the Hg(II) atom, lying on a twofold rotation axis, is four-coordinated in a distorted tetra-hedral geometry by an N,N'-bidentate diaza-fluoren-9-one ligand and two thio-cyanate anions. In the crystal, inter-molecular C-H⋯N and C-H⋯O hydrogen bonds are effective in the stabilization of the structure.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level. [Symmetry code: (i) -x+1, y, -z+1/2.]
Fig. 2.
Fig. 2.
The packing diagram of the title compound. Intermolecular C—H···O and C—H···N hydrogen bonds are shown as blue dashed lines.
See this image and copyright information in PMC

References

    1. Biju, A. R. & Rajasekharan, M. V. (2008). Polyhedron, 27, 2065–2068.
    1. Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.
    1. Farrugia, L. J. (1999). J. Appl. Cryst. 32, 837–838.
    1. Henderson, L. J. Jr, Fronczek, F. R. & Cherry, W. R. (1984). J. Am. Chem. Soc. 106, 5876–5879.
    1. Kulkarni, P., Padhye, S., Sinn, E., Anson, C. E. & Powell, A. K. (2002). Inorg. Chim. Acta, 332, 167–175.