Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2011 May 1;67(Pt 5):o1260-1.
doi: 10.1107/S1600536811015820. Epub 2011 Apr 29.

Triethyl-ammonium (S)-(-)-O-[1-(2-naphth-yl)eth-yl] (4-meth-oxy-phen-yl)dithio-phospho-nate

Triethyl-ammonium (S)-(-)-O-[1-(2-naphth-yl)eth-yl] (4-meth-oxy-phen-yl)dithio-phospho-nate

Samet Solak et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The crystal structure of the title compound, C(6)H(16)N(+)·C(19)H(18)O(2)PS(2) (-), consists of the dithio-phospho-nate anions and the triethyl-ammonium cations, which are linked by N-H⋯S hydrogen bonds and weak C-H⋯O hydrogen bonds. In the anion, the benzene ring is oriented with respect to the naphthalene ring system at a dihedral angle of 24.92 (5)°. In the crystal, weak C-H⋯π inter-actions also occur.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of the title molecule with the atom-numbering scheme. Displacement ellipsoids are drawn at the 50% probability level. C—H···O hydrogen bond is shown as dashed line.
Fig. 2.
Fig. 2.
A view of the crystal packing of the title compound. The C-H···O and N-H···S hydrogen bonds are shown as dashed lines [H-atoms not involved in hydrogen bonding have been omitted for clarity].

Similar articles

Cited by

References

    1. Alberti, E., Ardizzoia, G. A., Brenna, S., Castelli, F., Gali, S. & Maspero, A. (2007). Polyhedron, 26, 958–966.
    1. Allen, F. H., Kennard, O., Watson, D. G., Brammer, L., Orpen, A. G. & Taylor, R. (1987). J. Chem. Soc. Perkin Trans. 2, pp. S1–19.
    1. Bruker (2005). SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Bruker (2007). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
    1. Farrugia, L. J. (1997). J. Appl. Cryst. 30, 565.