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. 2011 Jun 1;67(Pt 6):m660.
doi: 10.1107/S1600536811015704. Epub 2011 May 7.

Tetra-chloridobis(dibenzyl sulfoxide-κO)tin(IV)

Thy Chun Keng  1 , Kong Mun Lo, Seik Weng Ng
Affiliations

Tetra-chloridobis(dibenzyl sulfoxide-κO)tin(IV)

Thy Chun Keng et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The six-coordinate Sn(IV) atom in the title compound, [SnCl(4)(C(14)H(14)OS)(2)], exists in a cis-SnCl(4)O(2) octa-hedral geometry. Of the four Cl atoms, two are close to adjacent S atoms [Cl⋯S = 3.320 (1) and 3.376 (1) Å]; the Sn-Cl bonds involving these two Cl atoms are longer than the other two Sn-Cl bonds.

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Figures

Fig. 1.
Fig. 1.
Anisotropic displacement ellipsoid plot (Barbour, 2001) of SnCl4(C14H14OS)2 at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
See this image and copyright information in PMC

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