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. 2011 Jun 1;67(Pt 6):m696.
doi: 10.1107/S1600536811013584. Epub 2011 May 7.

Bis(dimethyl-ammonium) tetra-chlorido-dimethyl-stannate(IV)

Tidiane Diop, Libasse Diop, Francois Michaud

Bis(dimethyl-ammonium) tetra-chlorido-dimethyl-stannate(IV)

Tidiane Diop et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

Regular crystals of the title compound, (C(2)H(8)N)(2)[Sn(CH(3))(2)Cl(4)], were obtained by reacting SnMe(2)Cl(2) with (CH(3))(2)NH·HCl in ethanol in a 1:1 ratio. The Sn atom lies on a center of symmetry and is six-coordinated. It has a distorted octahedral SnC(2)Cl(4) environment with the Cl atoms in cis positions. The Cl atoms are connected to dimethyl-ammonium cations through N-H⋯Cl hydrogen bonds, forming an infinite chain extending parallel to [010].

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Figures

Fig. 1.
Fig. 1.
Molecular packing around one anion implying hydrogen bonds (dashed lines) with the atom numbering used and 50% probability displacement elipsoids. Symmetry operations : ['] -x, -y, -z; [''] x, y+1,z, ['''] -x, -y, -z.
See this image and copyright information in PMC

References

    1. Altomare, A., Burla, M. C., Camalli, M., Cascarano, G. L., Giacovazzo, C., Guagliardi, A., Moliterni, A. G. G., Polidori, G. & Spagna, R. (1999). J. Appl. Cryst. 32, 115–119.
    1. Casas, J., Castineiras, A., Couce, M. D., Martinez, G., Sordo, J. & Varela, J. M. (1996). J. Organomet. Chem. 517, 165–172.
    1. Crowe, A. J. (1994). Metal Complexes in Cancer Chemotherapy, edited by S. P. Friccker. London: Chapman and Hall.
    1. Diasse-Sarr, A., Diop, L., Mahon, M. F. & Molloy, K. C. (1997). Main Group Met. Chem. 20, 223–229.
    1. Diop, T., Diop, L., Molloy, K. C. K. & Kocioc-Köhn, G. (2011). Acta Cryst E67, m203–m204. - PMC - PubMed