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. 2011 Jun 1;67(Pt 6):m749-50.
doi: 10.1107/S1600536811017144. Epub 2011 May 14.

[μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κN,C:κC,N']bis[(1,3-diphenylpropane-1,3-dionato-κO,O')palladium(II)](Pd-Pd)

Simona Maggini  1 , Peter S White
Affiliations

[μ-1,3-Dioxo-1,3-bis(pyridin-2-yl)propane-2,2-diido-κN,C:κC,N']bis[(1,3-diphenylpropane-1,3-dionato-κO,O')palladium(II)](Pd-Pd)

Simona Maggini et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, [Pd(2)(C(13)H(8)N(2)O(2))(C(15)H(11)O(2))(2)], crystallized from a mixture of ethanol and n-hexa-nes. The structure is the first example of β-diketonate in a dianionic κ(2)C-coordination complex containing a Pd(II)-Pd(II) bond. Both Pd(II) atoms adopt a pseudo square-planar coordination geometry. The mol-ecular packing involves π-inter-actions between the phenyl rings of the 1,3-diphenyl-propane-1,3-dionato ligands with centroid-centroid distances in the range 3.823 (2)-3.868 (2) Å.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of [Pd2(C15H11O2)2(C13H8N2O2)]. Displacement ellipsoids are drawn at the 50% probability level.
See this image and copyright information in PMC

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