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. 2011 Jun 1;67(Pt 6):o1338.
doi: 10.1107/S1600536811014693. Epub 2011 May 7.

2-[4-(Methyl-sulfan-yl)phen-yl]naphtho[1,8-de][1,3,2]diaza-borinane

Cathryn A Slabber  1 , Matthew P Akerman, Ross S Robinson
Affiliations

2-[4-(Methyl-sulfan-yl)phen-yl]naphtho[1,8-de][1,3,2]diaza-borinane

Cathryn A Slabber et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(17)H(15)BN(2)S, is one member in a series of diaza-borinanes featuring substitution at the 1-, 2- and 3-positions in the nitro-gen-boron heterocycle. The dihedral angle between the mean planes of the naphthalene and phenyl ring systems is 19.86 (6)°. In the crystal structure, two C-H⋯π inter-actions link the mol-ecules into sheets which lie parallel to the bc plane. There is a π-π inter-action between each pair of centrosymmetrically related sheets [centroid-centroid distance = 3.5922 (8) Å].

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Figures

Fig. 1.
Fig. 1.
A view of the molecule showing the numbering scheme. Displacement ellipsoids are drawn at the 30% probability level.
See this image and copyright information in PMC

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