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. 2011 Jun 1;67(Pt 6):o1482.
doi: 10.1107/S1600536811016837. Epub 2011 May 20.

(Anthracen-9-ylmeth-yl)benzyl-ammonium chloride

Jian-Rong Han, Wei Wang, Xiao-Li Zhen, Xia Tian, Shou-Xin Liu

(Anthracen-9-ylmeth-yl)benzyl-ammonium chloride

Jian-Rong Han et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(22)H(20)N(+)·Cl(-), the anthracene system makes a dihedral angle of 72.65 (4)° with the benzene ring. The C-N-C-C torsion angles in the chain connecting the benzene ring and anthracene system are 52.24 (15) and -170.73 (11)°. The crystal structure is stabilized by inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds, which link the mol-ecules into tetra-mers about inversion centers.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title complex, with 50% probablity ellipsoids.
Fig. 2.
Fig. 2.
Unit cell packing of the title complex, showing hydrogen bonded tetramers.
See this image and copyright information in PMC

References

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