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. 2011 Jun 1;67(Pt 6):o1501.
doi: 10.1107/S1600536811018782. Epub 2011 May 25.

(1S,3S)-Methyl 6,7-dimeth-oxy-1-phenyl-1,2,3,4-tetra-hydro-isoquinoline-3-carboxyl-ate

Tricia Naicker, Thavendran Govender, Hendrik G Kruger, Glenn E M Maguire

(1S,3S)-Methyl 6,7-dimeth-oxy-1-phenyl-1,2,3,4-tetra-hydro-isoquinoline-3-carboxyl-ate

Tricia Naicker et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, C(19)H(21)NO(4), an organocatalyst with a tetra-hydro-isoquinoline backbone, the heterocyclic ring assumes a half-boat conformation. The dihedral angle between the aromatic rings is 82.93 (8)°. In the crystal, mol-ecules are linked via N-H⋯O and C-H⋯O hydrogen bonds, forming a layer parallel to (10[Formula: see text]).

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound with the atom numbering scheme. Displacement ellipsoids are drawn at the 40% probability level. Hydrogen atoms have been omitted for clarity.
Fig. 2.
Fig. 2.
A partial projection of the title compound, viewed along the a axis.
See this image and copyright information in PMC

References

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