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. 2011 Jun 1;67(Pt 6):o1551-2.
doi: 10.1107/S1600536811019490. Epub 2011 May 28.

Benzyl-sulfamide

Thomas Gelbrich  1 , Mairi F Haddow, Ulrich J Griesser
Affiliations

Benzyl-sulfamide

Thomas Gelbrich et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

THE CRYSTAL OF THE TITLE COMPOUND [SYSTEMATIC NAME: 4-(benzyl-amino)-benzene-sulfonamide], C(13)H(14)N(2)O(2)S, displays a hydrogen-bonded framework structure. Mol-ecules are doubly N-H⋯O hydrogen bonded to one another via their NH(2) groups and sulfonyl O atoms. These inter-actions generate a hydrogen-bonded ladder structure parallel to the a axis, which contains fused R(2) (2)(8) rings. The NH group serves as the hydrogen-bond donor for a second set of inter-molecular N-H⋯O=S inter-actions.

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Figures

Fig. 1.
Fig. 1.
The molecular structure with displacement ellipsoids drawn at the 50% probability level. Hydrogen atoms are shown as spheres of arbitrary size.
Fig. 2.
Fig. 2.
Ladder structure parallel to [100] formed by H-bonds involving the NH2 group. The interactions between the NH group and O2 are indicated by arrows. O and H atoms directly engaged in N–H···O bonds are drawn as balls.
Fig. 3.
Fig. 3.
H-bonded framework structure viewed parallel to the a-axis, with H-bonds indicated by arrows.
See this image and copyright information in PMC

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