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. 2011 Aug 24;23(33):332201.
doi: 10.1088/0953-8984/23/33/332201. Epub 2011 Jul 21.

Orthorhombic polar Nd-doped BiFeO3 thin film on MgO substrate

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Orthorhombic polar Nd-doped BiFeO3 thin film on MgO substrate

I N Leontyev et al. J Phys Condens Matter. .

Abstract

A Nd-doped BiFeO(3) thin film deposited on MgO substrate was studied by synchrotron diffraction. The ferroelectric nature of the film is proven by in-plane remanent polarization measurement. The highest possible symmetry of the film is determined to be orthorhombic, within the Fm2m space group. Such a structure is rotated by 45° with respect to the substrate and is consistent with tilts of oxygen octahedra doubling the unit cell. This polar structure presents a rather unusual strain-accommodation mechanism.

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