Orthorhombic polar Nd-doped BiFeO3 thin film on MgO substrate
- PMID: 21775802
- DOI: 10.1088/0953-8984/23/33/332201
Orthorhombic polar Nd-doped BiFeO3 thin film on MgO substrate
Abstract
A Nd-doped BiFeO(3) thin film deposited on MgO substrate was studied by synchrotron diffraction. The ferroelectric nature of the film is proven by in-plane remanent polarization measurement. The highest possible symmetry of the film is determined to be orthorhombic, within the Fm2m space group. Such a structure is rotated by 45° with respect to the substrate and is consistent with tilts of oxygen octahedra doubling the unit cell. This polar structure presents a rather unusual strain-accommodation mechanism.
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