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. 2011 Sep 5;50(17):8384-91.
doi: 10.1021/ic200943s. Epub 2011 Jul 27.

Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules

Haralampos N Miras  1 , Daniel Stone, De-Liang Long, Eric J L McInnes, Paul Kögerler, Leroy Cronin
Affiliations

Exploring the structure and properties of transition metal templated {VM17(VO4)2} Dawson-like capsules

Haralampos N Miras et al. Inorg Chem. .

Abstract

Vanadate(V)-templated Dawson-type capsules {V(IV)M(VI)(17)(VO(4))(2)} (M = Mo, W; 1-2) have been synthesized and investigated by electrochemical methods in aqueous and organic media using spectroscopic techniques, EPR, UV-vis/NIR, IR, and CSI-MS (cryospray ionization mass spec.), and the clusters have been examined in the solid state by magnetic studies. The collision-induced dissociation (CID-MS) studies confirmed the solution structures as well as helped pinpoint the position of the vanadium ion on the {VM(17)}-type shell, which was corroborated by EPR and theoretical studies.

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