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. 2011 Jul 1;67(Pt 7):m858.
doi: 10.1107/S1600536811020885. Epub 2011 Jun 4.

Bis[4-bromo-2-(ethyl-imino-meth-yl)phenolato-κN,O]nickel(II)

Fu Li Chen  1 , Shu Hua Zhang, Jing Jing Guo, Yi Dong Zhang, Chao Feng
Affiliations

Bis[4-bromo-2-(ethyl-imino-meth-yl)phenolato-κN,O]nickel(II)

Fu Li Chen et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title complex, [Ni(C(9)H(9)BrNO)(2)], the Ni(II) ion lies on an inversion centre and is coordinated in a slightly distorted square-planar geometry by two N atoms and two O atoms from two symmetry-related bidentate 4-bromo-2-(ethyl-imino-meth-yl)phenolate ligands. The complex forms a one-dimensional chain in the crystal structure through short C-H⋯Br contacts (H⋯Br = 3.009 Å).

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title complex, showing 30% probability displacement ellipsoids. H atoms were omitted.
Fig. 2.
Fig. 2.
Packing drawing of the title compound.
See this image and copyright information in PMC

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