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. 2011 Jul 1;67(Pt 7):o1628.
doi: 10.1107/S1600536811021714. Epub 2011 Jun 11.

2-(Naphthalen-1-yl-amino)-cyclo-hexa-nol

Rachid Outouch, Brahim Boualy, Mustapha Ait Ali, Larbi El Firdoussi, Corrado Rizzoli

2-(Naphthalen-1-yl-amino)-cyclo-hexa-nol

Rachid Outouch et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The title compound, C(16)H(19)NO, was synthesized under solvent-free conditions by reaction of 7-oxa-bicyclo-[4.1.0]heptane and naphthalen-1-amine in the presence of Ca(CF(3)COO)(2) as catalyst. The cyclo-hexane ring adopts a chair conformation. In the crystal, mol-ecules are linked by inter-molecular N-H⋯O hydrogen bonds and C-H⋯π inter-actions into chains parallel to the c axis.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level.
Fig. 2.
Fig. 2.
Packing diagram of the title compound showing the formation of molecular chains along the a axis via intermolecular N—H···O hydrogen bonds (red dashed lines) and C—H···π interactions (green dashed lines).
See this image and copyright information in PMC

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