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. 2011 Jul 1;67(Pt 7):o1804.
doi: 10.1107/S1600536811023786. Epub 2011 Jun 25.

1-(5-Bromo-2-oxoindolin-3-yl-idene)thio-semicarbazide acetonitrile monosolvate

Fernanda Rosi Soares Pederzolli, Leandro Bresolin, Vanessa Santana Carratu, Aline Locatelli, Adriano Bof de Oliveira

1-(5-Bromo-2-oxoindolin-3-yl-idene)thio-semicarbazide acetonitrile monosolvate

Fernanda Rosi Soares Pederzolli et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the crystal structure of the title compound, C(9)H(7)BrN(4)OS·C(2)H(3)N, the mol-ecules are connected via N-H⋯O and N-H⋯S inter-actions into zigzag chains perpendicular to [001]. The mol-ecules in these chains are additionally linked to acetonitrile solvent mol-ecules through N-H⋯N hydrogen bonding. The mol-ecules are arranged in layers and are stacked in the direction of the c axis indicative of π-π inter-actions, with distance = 3.381 (7) Å for the C⋯C interaction parallel to [001]. An intra-molecular N-H⋯O hydrogen bond is also observed in the main mol-ecule.

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Figures

Fig. 1.
Fig. 1.
: The molecular structure of the title compound with labelling and displacement ellipsoids drawn at the 50% probability level.
Fig. 2.
Fig. 2.
: Crystal structure of the title compound viewed in the direction of the crystallographic c axis. Hydrogen bonding is indicated as dashed lines.
See this image and copyright information in PMC

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