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. 2011 Oct 7;13(19):5252-5.
doi: 10.1021/ol2021302. Epub 2011 Sep 2.

Palladium-catalyzed regioselective C-S bond cleavage of thiophenes

Huanan Huang  1 , Jing Li, Christophe Lescop, Zheng Duan
Affiliations

Palladium-catalyzed regioselective C-S bond cleavage of thiophenes

Huanan Huang et al. Org Lett. .

Abstract

Herein, a Pd-catalyzed reaction of simple and diverse bromothiophenes with alkynes via regioselective C-S bond activation is reported. This provides a new approach to prepare sulfur-based heterocycles and fulvenes.

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