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. 2011 Nov 7;47(41):11444-6.
doi: 10.1039/c1cc14537a. Epub 2011 Sep 21.

Azidomethyl-ruthenocene: facile synthesis of a useful metallocene derivative and its application in the 'click' labelling of biomolecules

Malay Patra  1 , Nils Metzler-Nolte
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Azidomethyl-ruthenocene: facile synthesis of a useful metallocene derivative and its application in the 'click' labelling of biomolecules

Malay Patra et al. Chem Commun (Camb). .

Abstract

A convenient synthesis of azidomethyl-ruthenocene and its use in the covalent labelling of amino acids, peptides and a peptide nucleic acid (PNA) monomer derivative by Cu(I) catalyzed azide-alkyne coupling (Cu-AAC, "click chemistry") are described.

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