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. 2011 Nov 28;47(44):12065-7.
doi: 10.1039/c1cc15004a. Epub 2011 Sep 30.

Artificial metalloenzymes for olefin metathesis based on the biotin-(strept)avidin technology

Cheikh Lo  1 , Mark R Ringenberg, David Gnandt, Yvonne Wilson, Thomas R Ward
Affiliations

Artificial metalloenzymes for olefin metathesis based on the biotin-(strept)avidin technology

Cheikh Lo et al. Chem Commun (Camb). .

Abstract

Incorporation of a biotinylated Hoveyda-Grubbs catalyst within (strept)avidin affords artificial metalloenzymes for the ring-closing metathesis of N-tosyl diallylamine in aqueous solution. Optimization of the performance can be achieved either by chemical or genetic means.

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