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. 2011 Nov 4;13(21):5782-3.
doi: 10.1021/ol202349g. Epub 2011 Oct 4.

Fast and protecting-group-free synthesis of (±)-subincanadine C

Fangmiao Yu  1 , Bin Cheng, Hongbin Zhai
Affiliations

Fast and protecting-group-free synthesis of (±)-subincanadine C

Fangmiao Yu et al. Org Lett. .

Abstract

The first total synthesis of (±)-subincanadine C has been accomplished in a protecting-group-free fashion. This pentacyclic indole alkaloid was synthesized in six steps from the known intermediate 4, featuring Ni(COD)(2)-mediated intramolecular Michael addition as a key transformation.

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