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. 2011 Nov 18;13(22):6002-5.
doi: 10.1021/ol2024423. Epub 2011 Oct 20.

Highly diastereoselective synthesis of 1-pyrrolines via SnCl4-promoted [3 + 2] cycloaddition between activated donor-acceptor cyclopropanes and nitriles

Gopal Sathishkannan  1 , Kannupal Srinivasan
Affiliations

Highly diastereoselective synthesis of 1-pyrrolines via SnCl4-promoted [3 + 2] cycloaddition between activated donor-acceptor cyclopropanes and nitriles

Gopal Sathishkannan et al. Org Lett. .

Abstract

Activated donor-acceptor cyclopropanes underwent formal [3 + 2] cycloaddition with nitriles in the presence of SnCl(4). The product 1-pyrrolines were isolated as single cis-diastereomers in moderate to good yields.

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