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. 2011 Oct 1;67(Pt 10):o2760.
doi: 10.1107/S1600536811038815. Epub 2011 Sep 30.

2-{(1E)-1-[(3-{(E)-[1-(2-Hy-droxy-4-meth-oxy-phen-yl)ethyl-idene]amino}-2,2-di-methyl-prop-yl)imino]-eth-yl}-5-meth-oxy-phenol

2-{(1E)-1-[(3-{(E)-[1-(2-Hy-droxy-4-meth-oxy-phen-yl)ethyl-idene]amino}-2,2-di-methyl-prop-yl)imino]-eth-yl}-5-meth-oxy-phenol

Akbar Ghaemi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

Mol-ecules of the title compound, C(23)H(30)N(2)O(4), are located on a crystallographic mirror plane. The mol-ecule has a curved shape with the dihedral angle formed between the two benzene rings being 55.26 (5)°. Intra-molecular O-H⋯N hydrogen bonds are noted. In the crystal, supra-molecular layers are formed in the ac plane owing to the presence of C-H⋯π inter-actions.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I) showing the atom-labelling scheme and displacement ellipsoids at the 50% probability level. The molecule has mirror symmetry and the unlabelled atoms are related by the symmetry operation x, 3/2 - y, z.
Fig. 2.
Fig. 2.
Supramolecular layer in the ac plane in (I) sustained by C—H···π interactions shown as purple dashed lines.
Fig. 3.
Fig. 3.
A view in projection down the c axis of the unit-cell contents of (I), highlighting the stacking of layers along the b axis. The C—H···π interactions are shown as purple dashed lines.

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