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. 2011 Oct 1;67(Pt 10):m1354.
doi: 10.1107/S1600536811035355. Epub 2011 Sep 14.

Dicaesium diaqua-bis-(methyl-ene-diphospho-nato-κO,O')cobaltate(II)

Kina van Merwe  1 , Hendrik G Visser, Johan A Venter
Affiliations

Dicaesium diaqua-bis-(methyl-ene-diphospho-nato-κO,O')cobaltate(II)

Kina van Merwe et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The asymmetric unit of the title compound, Cs(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], is comprised of one bidentate methyl-enediphospho-nate ligand and one water mol-ecule which are coordinated to the Co(II) atom, as well as a caesium counter-cation. The Co atom occupies a special position on a crystallographic inversion center. The caesium ion is octa-hedrally coordinated by six O atoms with Cs-O distances ranging from 3.119 (2) to 3.296 (2) Å. A three-dimensional network is formed through O-H⋯O hydrogen bonds.

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Figures

Fig. 1.
Fig. 1.
Representation of the title compound, showing the numbering scheme and displacement ellipsoids drawn at the 50% probability level. [Symmetry code: (i) 1 - x, -y, 1 - z].
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