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. 2012 Jan 7;48(2):248-50.
doi: 10.1039/c1cc14275e. Epub 2011 Nov 16.

Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity

Arindam Modak  1 , Mahasweta Nandi, John Mondal, Asim Bhaumik
Affiliations

Porphyrin based porous organic polymers: novel synthetic strategy and exceptionally high CO2 adsorption capacity

Arindam Modak et al. Chem Commun (Camb). .

Abstract

Iron containing porous organic polymers (Fe-POPs) have been synthesized by a facile one-pot bottom-up approach to porphyrin chemistry by an extended aromatic substitution reaction between pyrrole and aromatic dialdehydes in the presence of small amount of Fe(III). The Fe-POPs possess very high BET surface area, large micropores and showed excellent CO(2) capture (~19 wt%) at 273 K/1 bar.

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