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. 2011 Aug 1;67(Pt 8):o2154.
doi: 10.1107/S1600536811029412. Epub 2011 Jul 30.

Pyridine-2,3-diamine

Richard Betz  1 , Thomas Gerber, Eric Hosten, Henk Schalekamp
Affiliations

Pyridine-2,3-diamine

Richard Betz et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The mol-ecule of the title pyridine derivative, C(5)H(7)N(3), shows approximately non-crystallographic C(s) symmetry. Intra-cyclic angles cover the range 117.50 (14)-123.03 (15)°. In the crystal, N-H⋯N hydrogen bonds connect mol-ecules into a three-dimensional network. The closest inter-centroid distance between two π-systems occurs with the c-axis repeat at 3.9064 (12) Å.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of the title compound, with atom labels and anisotropic displacement ellipsoids (drawn at 50% probability level).
Fig. 2.
Fig. 2.
Intermolecular contacts, viewed approximately along [0 0 1]. Symmetry operators: iy, -x, z - 1/2; iiy, -x, z + 1/2; iii -y, x, z - 1/2; iv -y, x, z + 1/2; v -y + 1/2, -x + 1/2, z - 1/2; vi -y + 1/2, -x + 1/2, z + 1/2.
Fig. 3.
Fig. 3.
Molecular packing of the title compound, viewed along [0 0 - 1] (anisotropic displacement ellipsoids drawn at 50% probability level).
See this image and copyright information in PMC

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