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. 2012 Jan 21;48(6):868-70.
doi: 10.1039/c1cc16646h. Epub 2011 Dec 1.

New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation

Victor Mougel  1 , Jacques Pécaut, Marinella Mazzanti
Affiliations

New polynuclear U(IV)-U(V) complexes from U(IV) mediated uranyl(V) disproportionation

Victor Mougel et al. Chem Commun (Camb). .

Abstract

U(IV) promotes the disproportionation of otherwise stable uranyl(V) Schiff base complexes affording U(IV)-U(V) oxo clusters with new geometries and the first example of a U(IV)···UO(2)(+) cation-cation interaction.

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