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. 2012 Jan 9;51(2):528-32.
doi: 10.1002/anie.201106299. Epub 2011 Dec 1.

Alkylboronic esters from copper-catalyzed borylation of primary and secondary alkyl halides and pseudohalides

Chu-Ting Yang  1 , Zhen-Qi Zhang, Hazmi Tajuddin, Chen-Cheng Wu, Jun Liang, Jing-Hui Liu, Yao Fu, Maria Czyzewska, Patrick G Steel, Todd B Marder, Lei Liu
Affiliations

Alkylboronic esters from copper-catalyzed borylation of primary and secondary alkyl halides and pseudohalides

Chu-Ting Yang et al. Angew Chem Int Ed Engl. .

Abstract

Easy access: An unprecedented copper-catalyzed cross-coupling reaction of the title compounds with diboron reagents is described (see scheme; Ts = 4-toluenesulfonyl). This reaction can be used to prepare both primary and secondary alkylboronic esters having diverse structures and functional groups. The resulting products would be difficult to access by other means.

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