Radicals in transition metal catalyzed reactions? transition metal catalyzed radical reactions? - a fruitful interplay anyway: part 2. Radical catalysis by group 8 and 9 elements
- PMID: 22143610
- DOI: 10.1007/128_2011_285
Radicals in transition metal catalyzed reactions? transition metal catalyzed radical reactions? - a fruitful interplay anyway: part 2. Radical catalysis by group 8 and 9 elements
Abstract
This review summarizes the current status of transition metal catalyzed reactions involving radical intermediates in organic chemistry. This part focuses on radical-based methods catalyzed by group 8 and group 9 metal complexes. Reductive and redox-neutral coupling methods catalyzed by low-valent metal complexes as well as catalytic oxidative C-C bond formations are reviewed.
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