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. 2011 Dec 1;67(Pt 12):o3198.
doi: 10.1107/S1600536811046009. Epub 2011 Nov 5.

(1-Adamant-yl)(3-amino-phen-yl)methanone

Michal Rouchal, Marek Nečas, Robert Vícha

(1-Adamant-yl)(3-amino-phen-yl)methanone

Michal Rouchal et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the crystal sructure of the title compound, C(17)H(21)NO, the mol-ecular packing is stabilized by inter-molecular N-H⋯O hydrogen bonds and additional weak N-H⋯π inter-actions, forming chains that propagate along the b axis. Conjugation of the carbonyl group and the benzene ring is rather attenuated due to a twisting of the carbonyl group from the plane of the benzene ring [torsion angle = 27.1 (2)°].

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Figures

Fig. 1.
Fig. 1.
A thermal ellipsoid plot (50% probability) of the asymmetric unit. H-Atoms are shown as small spheres at arbitrary radii.
Fig. 2.
Fig. 2.
The H-bonded chains of the molecules of title compound arranged parallel to the b-axis. H-atoms have been omitted (except for those participating in H-bonds) for clarity. Cg1 is centre of gravity of C12—C17. Symmetry codes: (i) -x + 1, y - 1/2, -z + 1/2; (ii) -x, y - 1/2, -z + 1/2.
See this image and copyright information in PMC

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