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. 2011 Nov;67(Pt 11):m1571.
doi: 10.1107/S1600536811042759. Epub 2011 Oct 22.

[N,N-Bis(diphenyl-phosphan-yl)benzyl-amine-κP,P']dichloridonickel(II) dichloro-methane monosolvate

Bang-Shao Yin  1 , Tian-Bao Li, Ming-Sheng Yang
Affiliations

[N,N-Bis(diphenyl-phosphan-yl)benzyl-amine-κP,P']dichloridonickel(II) dichloro-methane monosolvate

Bang-Shao Yin et al. Acta Crystallogr Sect E Struct Rep Online. 2011 Nov.

Abstract

In the title solvated complex, [NiCl(2)(C(31)H(27)NP(2))]·CH(2)Cl(2), the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the chelating N,N-bis-(diphenyl-phosphan-yl)benzyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. In the crystal, the components are linked by C-H⋯Cl inter-actions.

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Figures

Fig. 1.
Fig. 1.
The molecular structure of (I). Displacement ellipsoids are drawn at the 30% probability level and H atoms are shown as small spheres of arbitrary radius.
Fig. 2.
Fig. 2.
The packing for (I).
See this image and copyright information in PMC

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