Skip to main page content
U.S. flag

An official website of the United States government

Dot gov

The .gov means it’s official.
Federal government websites often end in .gov or .mil. Before sharing sensitive information, make sure you’re on a federal government site.

Https

The site is secure.
The https:// ensures that you are connecting to the official website and that any information you provide is encrypted and transmitted securely.

Access keys NCBI Homepage MyNCBI Homepage Main Content Main Navigation
. 2011 Nov;67(Pt 11):m1572.
doi: 10.1107/S1600536811042760. Epub 2011 Oct 22.

[N,N-Bis(diphenyl-phosphan-yl)propanamine-κP,P']dichloridonickel(II)

Bang-Shao Yin  1 , Tian-Bao Li, Ming-Sheng Yang
Affiliations

[N,N-Bis(diphenyl-phosphan-yl)propanamine-κP,P']dichloridonickel(II)

Bang-Shao Yin et al. Acta Crystallogr Sect E Struct Rep Online. 2011 Nov.

Abstract

In the title complex, [NiCl(2)(C(27)H(27)NP(2))], the Ni(2+) ion is coordinated by two chloride ions and two P atoms of the bidentate N,N-bis-(diphenyl-phosphan-yl)propyl ligand to generate a strongly distorted cis-NiCl(2)P(2) square-planar geometry for the metal ion. A NiP(2)N rhombus occurs within the chelating ligand.

PubMed Disclaimer

Figures

Fig. 1.
Fig. 1.
The molecular structure of (I). Displacement ellipsoids are drawn at the 30% probability level and H atoms are shown as small spheres of arbitrary radius.
Fig. 2.
Fig. 2.
The packing for (I).
See this image and copyright information in PMC

References

    1. Rigaku/MSC (2005). CrystalClear and CrystalStructure Rigaku/MSC Inc., The Woodlands, Texas, USA.
    1. Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. - PubMed
    1. Sun, Z., Zhu, F. & Lin, S. (2006). Appl. Organomet. Chem. 20, 175–180.
    1. Yin, B.-S., Li, T.-B. & Yang, M.-S. (2011). Acta Cryst. E67, m1571. - PMC - PubMed