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. 2012 Feb 11;48(13):1922-4.
doi: 10.1039/c2cc16758a. Epub 2012 Jan 9.

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

David Rosa  1 , Arturo Orellana
Affiliations

Synthesis of α-indanones via intramolecular direct arylation with cyclopropanol-derived homoenolates

David Rosa et al. Chem Commun (Camb). .

Abstract

A palladium-catalysed, tandem cyclopropanol rearrangement and direct arylation approach for the synthesis of 1-indanones is reported. The reaction is generally high yielding, uses oxygen as the terminal oxidant and tolerates a range of functional groups on the aryl ring.

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