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. 2012 Jan 20;14(2):636-9.
doi: 10.1021/ol2032784. Epub 2012 Jan 9.

N-Directing group assisted rhodium-catalyzed aryl C-H addition to aryl aldehydes

Yang Li  1 , Xi-Sha Zhang, Kang Chen, Ke-Han He, Fei Pan, Bi-Jie Li, Zhang-Jie Shi
Affiliations

N-Directing group assisted rhodium-catalyzed aryl C-H addition to aryl aldehydes

Yang Li et al. Org Lett. .

Abstract

Direct aryl C-H addition to aryl aldehydes to produce biaryl methanols was reported via Rh catalysis with an N-containing directing group. The method is highly atom-, step-, and redox-economic. The procedure is robust, reliable, and compatible with water and air.

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