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. 2012 Feb 3;14(3):780-3.
doi: 10.1021/ol203318z. Epub 2012 Jan 18.

Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

Shiguang Pan  1 , Kohei Endo, Takanori Shibata
Affiliations

Ir(I)-catalyzed intermolecular regio- and enantioselective hydroamination of alkenes with heteroaromatic amines

Shiguang Pan et al. Org Lett. .

Abstract

A cationic Ir(I)-C(3)-TUNEPHOS complex catalyzed an intermolecular hydroamination of styrene derivatives with various heteroaromatic amines. The reaction gave Markovnikov products with perfect regioselectivity and good enantioselectivity under solvent-free conditions.

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