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. 2012 Jan;68(Pt 1):m33-4.
doi: 10.1107/S160053681105207X. Epub 2011 Dec 10.

Bis(tetra-phenyl-phospho-nium) bis-[N-(trifluoro-methyl-sulfon-yl)dithio-carbimato(2-)-κS,S']zincate(II)

Paula S Pinto, Mayura M M Rubinger, Silvana Guilardi, Drielly A Paixão, Marcelo R L Oliveira

Bis(tetra-phenyl-phospho-nium) bis-[N-(trifluoro-methyl-sulfon-yl)dithio-carbimato(2-)-κS,S']zincate(II)

Paula S Pinto et al. Acta Crystallogr Sect E Struct Rep Online. 2012 Jan.

Abstract

The title salt, (C(24)H(20)P)(2)[Zn(C(2)F(3)NO(2)S(3))(2)], consists of a complex dianion and two tetra-phenyl-phospho-nium cations. The Zn(II) ion displays a distorted tetra-hedral coordination environment with four S atoms from two S,S'-chelated N-(trifluoro-methyl-sulfonyl-)dithio-carbimate anions. In the crystal, besides the ionic inter-action of the oppositely charged ions, inter-molecular C-H⋯O inter-actions between cations and anions are observed. One of the cations inter-acts with an inversion-related equivalent by π-π stacking between phenyl rings, with a centroid-centroid distance of 3.932 (4) Å.

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Figures

Fig. 1.
Fig. 1.
Representation of the title compound, with displacement ellipsoids drawn at the 30% probability level.
See this image and copyright information in PMC

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