5',11'-Dihydro-dispiro-[cyclo-hexane-1,6'-indolo[3,2-b]carbazole-12',1''-cyclo-hexa-ne]
- PMID: 22259386
- PMCID: PMC3254282
- DOI: 10.1107/S1600536811051208
5',11'-Dihydro-dispiro-[cyclo-hexane-1,6'-indolo[3,2-b]carbazole-12',1''-cyclo-hexa-ne]
Abstract
The title compound, C(28)H(30)N(2), is a symmetrical 2:2 product from the condensation of indole and cyclo-hexa-none. It is the only reported 5,11-dihydro-indolo[3,2-b]carbazole compound in which the spiro atoms are quaternary C atoms. Crystals were grown by vapor diffusion in a three-zone electric furnace. The mol-ecule resides on a crystallographic inversion center. The cyclo-hexyl rings are in a slightly distorted chair conformation, whereas the indole units and the spiro-carbons are coplanar within 0.014 Å.
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References
-
- Allen, F. H. (2002). Acta Cryst. B58, 380–388. - PubMed
-
- Brandenburg, K. (1999). DIAMOND Crystal Impact GbR, Bonn, Germany.
-
- Bruker (2007). APEX2, SADABS and SAINT-Plus Bruker AXS Inc., Madison, Wisconsin, USA.
-
- Bruno, I. J., Cole, J. C., Edgington, P. R., Kessler, M., Macrae, C. F., McCabe, P., Pearson, J. & Taylor, R. (2002). Acta Cryst. B58, 389–397. - PubMed
-
- Gu, R., Van Snick, S., Robeyns, K., Van Meervelt, L. & Dehaen, W. (2009). Org. Biomol. Chem. 7, 380–385. - PubMed
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