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. 2012 Feb 15;134(6):2934-7.
doi: 10.1021/ja211527q. Epub 2012 Feb 6.

Recycling of carbon and silicon wastes: room temperature formylation of N-H bonds using carbon dioxide and polymethylhydrosiloxane

Olivier Jacquet  1 , Christophe Das Neves Gomes, Michel Ephritikhine, Thibault Cantat
Affiliations

Recycling of carbon and silicon wastes: room temperature formylation of N-H bonds using carbon dioxide and polymethylhydrosiloxane

Olivier Jacquet et al. J Am Chem Soc. .

Abstract

A highly active organocatalytic system based on N-heterocyclic carbenes has been designed for the formylation of N-H bonds in a large variety of nitrogen molecules and heterocycles, using two chemical wastes: CO(2) and polymethylhydrosiloxane (PMHS).

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