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. 2012 Mar 19;18(12):3478-81.
doi: 10.1002/chem.201103242. Epub 2012 Feb 7.

Light-mediated heterogeneous cross dehydrogenative coupling reactions: metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

Magnus Rueping  1 , Jochen Zoller, David C Fabry, Konstantin Poscharny, René M Koenigs, Thomas E Weirich, Joachim Mayer
Affiliations

Light-mediated heterogeneous cross dehydrogenative coupling reactions: metal oxides as efficient, recyclable, photoredox catalysts in C-C bond-forming reactions

Magnus Rueping et al. Chemistry. .

Abstract

Let there be light: A heterogeneous photocatalytic system based on easily recyclable TiO(2) or ZnO allows cross dehydrogenative coupling reactions of tertiary amines. The newly developed protocols have successfully been applied to various C-C and C-P bond-forming reactions to provide nitro amines as well as amino ketones, nitriles and phosphonates.

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