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. 2012 Feb 1;68(Pt 2):m190.
doi: 10.1107/S1600536812001845. Epub 2012 Jan 21.

{3,14-Dimethyl-2,6,13,17-tetra-aza-tricyclo-[16.4.0.0]docosane-κN,N',N'',N''')bis-(nitrato-κO)copper(II)

Jong-Ha Choi, Md Abdus Subhan, Seik Weng Ng

{3,14-Dimethyl-2,6,13,17-tetra-aza-tricyclo-[16.4.0.0]docosane-κN,N',N'',N''')bis-(nitrato-κO)copper(II)

Jong-Ha Choi et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

The Cu(II) atom in the title compound, [Cu(NO(3))(2)(C(20)H(40)N(4))], is N,N',N'',N'''-chelated by the macrocyclic ligand: the four N atoms form a square, above and below which are located the O atoms of the nitrate ions. The metal atom exists in a tetra-gonally distorted octa-hedron, on a special position of [Formula: see text] site symmetry. One of the amino groups is hydrogen bonded to an O atom of the nitrate ion. The other amino group is hydrogen bonded to O atom of an adjacent mol-ecule, generating a supra-molecular dimeric hydrogen-bonded dinuclear aggregate.

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Figures

Fig. 1.
Fig. 1.
Thermal ellipsoid plot (Barbour, 2001) of Cu(NO3)2(C20H40N4) at the 70% probability level; hydrogen atoms are drawn as spheres of arbitrary radius.
See this image and copyright information in PMC

References

    1. Agilent (2011). CrysAlis PRO Agilent Technologies, Yarnton, England.
    1. Amadei, G. A., Dickman, M. H., Wazzeh, R. A., Dimmock, P. & Earley, J. E. (1999). Inorg. Chim. Acta, 288, 40–46.
    1. Barbour, L. J. (2001). J. Supramol. Chem. 1, 189–191.
    1. Choi, M.-H., Kim, B. J., Kim, I.-C., Kim, S.-Y., Kim, Y., Harrowfield, J. M., Lee, M. K., Mocerino, M., Rukmini, E., Skelton, B. W. & White, A. H. (2001). J. Chem. Soc. Dalton Trans. pp. 707–722.
    1. Choi, J.-H., Subhan, M. A., Ryoo, K. S. & Ng, S. W. (2012). Acta Cryst. E68, o102. - PMC - PubMed