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. 2012 Feb 1;68(Pt 2):m96.
doi: 10.1107/S1600536811054961. Epub 2012 Jan 7.

Aqua-[tris-(2-{5-[(4-methyl-phenyl)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine]-samarium(III) acetonitrile monosolvate

Sadegh Salehzadeh, Mahsa Mahdavian, Mehdi Khalaj

Aqua-[tris-(2-{5-[(4-methyl-phenyl)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine]-samarium(III) acetonitrile monosolvate

Sadegh Salehzadeh et al. Acta Crystallogr Sect E Struct Rep Online. .

Abstract

In the title compound, [Sm(C(48)H(45)N(10)O(3))(H(2)O)]·CH(3)CN, the Sm(III) ion is coordinated by the hepta-dentate tris-(2-{5-[(4-methyl-pheny)diazen-yl]-2-oxidobenzyl-idene-amino}-eth-yl)amine trianionic ligand and a water mol-ecule. The resulting SmN(4)O(4) coordination polyhedron is a distorted square anti-prism. In the crystal, complex mol-ecules are linked by O-H⋯O hydrogen bonds.

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Figures

Fig. 1.
Fig. 1.
A view of the structure of the title complex, with displacement ellipsoids drawn at the 50% probability level.
See this image and copyright information in PMC

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