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. 2012 Apr 16;51(16):3826-31.
doi: 10.1002/anie.201108061. Epub 2012 Mar 2.

Atropoisomeric (P,N) ligands for the highly enantioselective Pd-catalyzed intramolecular asymmetric α-arylation of α-branched aldehydes

Pradeep Nareddy  1 , Luca Mantilli, Laure Guénée, Clément Mazet
Affiliations

Atropoisomeric (P,N) ligands for the highly enantioselective Pd-catalyzed intramolecular asymmetric α-arylation of α-branched aldehydes

Pradeep Nareddy et al. Angew Chem Int Ed Engl. .

Abstract

Three-in-one: a short synthetic route readily gives access to a new class of chiral (P,N) ligands characterized by three distinct elements of chirality. These ligands are highly enantioselective in the challenging Pd-catalyzed intramolecular asymmetric α-arylation of α-branched aldehydes.

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