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. 2012 Mar 16;14(6):1363-5.
doi: 10.1021/ol300439r. Epub 2012 Mar 8.

Aryne insertion into I-I σ-bonds

Diego Rodríguez-Lojo  1 , Agustín Cobas, Diego Peña, Dolores Pérez, Enrique Guitián
Affiliations

Aryne insertion into I-I σ-bonds

Diego Rodríguez-Lojo et al. Org Lett. .

Abstract

A new protocol for the efficient synthesis of o-diiodoarenes has been developed. This method allows the synthesis of substituted and polycyclic o-diiodoarenes, which are difficult to obtain by classical methods. This diiodination process involves the formal insertion of arynes into the I-I σ-bond.

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