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. 2008;41(4):95-104.

Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and Imines

Ryan L Patman  1 , John F Bower, In Su Kim, Michael J Krische
Affiliations

Formation of C-C Bonds via Catalytic Hydrogenation and Transfer Hydrogenation: Vinylation, Allylation, and Enolate Addition of Carbonyl Compounds and Imines

Ryan L Patman et al. Aldrichimica Acta. 2008.
No abstract available

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Figures

Scheme 1
Scheme 1
Catalytic C-C Coupling via Hydrogenation and Transfer Hydrogenation.
Scheme 2
Scheme 2
Direct, Byproduct-Free Hydrogenative Coupling of Conjugated Alkynes to Activated Carbonyl Compounds and Imines Employing Cationic Rhodium Catalysts. (Ref. 27)
Scheme 3
Scheme 3
Unnatural α-Amino Acids via C-C-Bond-Forming Hydrogenation. (Ref. 28)
Scheme 4
Scheme 4
Enantioselective Carbonyl and Imine (Z)-Butadienylation via Rhodium-Catalyzed Hydrogenative Coupling of Acetylene. (Ref. 29,30)
Scheme 5
Scheme 5
Enantioselective Imine Vinylation via Iridium-Catalyzed Hydrogenative Coupling of Unconjugated Alkynes. (Ref. 32)
Scheme 6
Scheme 6
Enantio- and Diastereoselective Carbocyclizations of Acetylenic Aldehydes by the Rhodium-Catalyzed Asymmetric Hydrogenation. (Ref. 33)
Scheme 7
Scheme 7
Catalytic Carbonyl Addition via Iridium-Catalyzed Hydrogenative Coupling of Dimethylallene. (Ref. 39)
Scheme 8
Scheme 8
Coupling of Dienes to Alcohols or Aldehydes by the Iridium-Catalyzed Transfer Hydrogenation. (Ref. 41)
Scheme 9
Scheme 9
Coupling of Dienes to Alcohols or Aldehydes by the Ruthenium-Catalyzed Transfer Hydrogenation. (Ref. 42)
Scheme 10
Scheme 10
Carbonyl Propargylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed Transfer-Hydrogenative Coupling of 1,3-Enynes. (Ref. 43-45)
Scheme 11
Scheme 11
Enantioselective Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level via Iridium-Catalyzed Transfer-Hydrogenative Coupling of Allyl Acetate. (Ref. 46)
Scheme 12
Scheme 12
Reductive Aldol Cyclization via Catalytic Hydrogenation. (Ref. 64a,b)
Scheme 13
Scheme 13
Reductive Aldol Cyclization via Catalytic Hydrogenation. (Ref. 64b,c)
Scheme 14
Scheme 14
syn-Diastereoselective Hydrogen-Mediated Aldol Coupling Employing Cationic Rhodium Catalysts Ligated By Tri(2-furyl)phosphine. (Ref. 64e-g)
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References

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